Adsorpsi Pb Menggunakan Karbon Aktif dari Bambu Kuning (Bambusa Vulgaris Striata) Teraktivasi KOH

Ida Hasmita, Herlina S. Manap, Eka Marya Mistar

Abstract


Abstrak. Karbon aktif berbahan baku bambu kuning (Bambusa vulgaris striata) dipreparasi dengan KOH aktivasi untuk menyerap Timbal (Pb). Penelitian ini bertujuan untuk mengkaji daya adsorpsi Pb pada karbon aktif. Proses adsorpsi dilakukan dengan mengalirkan larutan Pb melewati unggun yang berisi karbon aktif. Variasi laju alir yang diaplikasikan adalah 5 mL/menit dan 10 mL/menit. Struktur mikro karbon aktif diamati dengan Scanning Electron Microscope (SEM). Hasil penelitian yang diperoleh menunjukkan daya adsorpsi Pb tertinggi pada laju alir 5 mL/menit, yaitu pada menit ke 100 menghasilkan konsentrasi effluent 5,82 mg/L.

Adsorption of Pb using activated carbon from Yellow Bamboo (Bambusa vulgaris striata) using KOH activation

Abstract. Activated carbon was prepared from Yellow bamboo (Bambusa vulgaris striata) via KOH activation to adsorb Pb ions from aqueous solutions. This research aimed to determine Pb adsorption using activated carbon. The adsorption process was performed by flowing the Pb solution through the fixed-bed column filled with the prepared activated carbon. The applied flow rate varied between 5 mL/min and 10 mL/min. The microstructure of activated carbon was observed using Scanning Electron Microscope (SEM). The obtained results showed that the highest Pb concentration at 5 mL/min was 5.82 mg/L.


Keywords


Adsorpsi; Karbon aktif; KOH; Pb; Bambusa vulgaris striata

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References


Ahmed, M.J., Theydan, S.K. (2014). Fluoroquinolones antibiotics adsorption onto microporous activated carbon from lignocellulosic biomass by microwave pyrolysis. Journal of the Taiwan Institute of Chemical Engineers:45: 219–226. https://doi.org/10.1016/j.jtice.2013.05.014.

Amoah, M., Assan, F., & Dadzie, P.D. (2020). Aboveground biomass, carbon storage and fuel values of Bambusa vulgaris, Oxynanteria abbyssinica and Bambusa vulgaris var.vitata plantations in the Bobiri forest reserve of Ghana. Journal of Sustainable Forestry: 39. https://doi.org/10.1080/10549811.2019.1608452.

Astuti, W., Kurniawan, B. (2015). Adsorpsi Pb2+ Dalam Limbah Cair Artifisial Menggunakan Sistem Adsorpsi Kolom Dengan Bahan Isian Abu Layang Batubara Serbuk dan Granular. Jurnal Bahan Alam Terbarukan, JBAT 4 (1) ; 27- 33. http://journal.unnes.ac.id/nju/index.php/jbat.

Cazetta, A.L., Vargas, A.M.M., Nogami, E.M., Kunita, M.H., Guilherme, M.R., Martins, A.C., Silva, T.L., Moraes, J.C.G. & Almeida, V.C. (2011). NaOH-activated carbon of high surface area produced from coconut shell: Kinetics and equilibrium studies from the methylene blue adsorption. Chemical Engineering Journal 174: 117-125. https://doi.org/10.1016/j.cej.2011.08.058.

González PG, Cuervo YBP. (2013). Physico chemical and microtextural characterization of activated carbons produced from water steam activation of three bamboo species. J Anal Appl Pyrolysis ;99:32–39. https://doi.org/10.1016/j.jaap.2012.11.004.

González PG, Quiroz TH, Gonzáles LG. (2014). The use ofexperimental design and response surface methodologiesfor the synthesis of chemically activated carbons producedfrom bamboo. Fuel Process Technol;127:133–139. https://doi.org/10.1016/j.fuproc.2014.05.035.

Kianoush, S., Sadeghi, M., Mood, M.B. (2015). Recent Advances in the Clinical Management of Lead Poisoning. Acta Medica Iranica. https://acta.tums.ac.ir/index.php/acta/article/view/4881.

Mahmoud, M.E., Kenawy, I.M.M., Hafez, M.M.A.H., Lashein. R.R. (2010). Removal, preconcentration and determination of trace heavy metal ions in water samples by AAS via chemically modified silica gel N-(1-carboxy-6-hydroxy) benzylidenepropylamine ion exchanger, Desalination 250;62–70. https://doi.org/10.1016/j.desal.2009.09.009.

Mistar EM, Ahmad S, Muslim A, Alfatah T, Supardan MD. (2018). Preparation and characterization of a high surface area ofactivated carbon from Bambusa vulgaris–Effect of NaOH activation and pyrolysis temperature. IOP Conf Ser Mater Sci Eng;334:012051. doi:10.1088/1757-899X/334/1/012051.

Mistar, E.M., Alfatah, T., Supardan, M.D. (2020). Synthesis and characterization of activated carbon from Bambusa vulgaris striata using two-step KOH activation. Journal of Materials Research and Technology;9(3):6278–6286. https://doi.org/10.1016/j.jmrt.2020.03.041.

Mohammadi, S. Z., Karimi, M.A., Afzali, D., Mansouri, F. (2010). Removal of Pb(II) from aqueous solutions using activated carbon from Sea-buckthorn stones by chemical activation. Desalination 262 ; 86-93. https://doi.org/10.1016/j.desal..05.048.

Mouni, L., Merabet, D., Bouzaza, A., Belkhiri, L. (2011). Adsorption of Pb(II) from aqueous solutions using activated carbon developed from Apricot stone. Desalination 276 (2011) 148–153. https://doi.org/10.1016/j.desal.2011.03.038.

Nath, A. J., Lal, R., & Das, O. K. (2015). Managing woody bamboos for carbon farming and carbon trading. Blob Ecology and Conservation, 3, 654–663. https://doi.org/10.1016/j.gecco.2015.03.002.

Prasad, M., Saxena, S., Amritphale, S.S., Chandra, N. (2000). Kinetics and isotherms for aqueous lead adsorption by natural minerals, Ind. Eng. Chem. Res. 39; 3034. https://doi.org/10.1021/ie9909082.

Rizal, S., Mistar, E.M., Rahman, A.A., Khalil, A.H.P.S., Oyekanmi, A.A., Olaiya, N.G., Abdullah, C.K., Alfatah, T. (2021). Bionanocarbon functional material characterisation and enhancement properties in nonwoven kenaf fibre nanocomposites. Polymers, 13, 2303. https://doi.org/10.3390/polym13142303.

Sethia G, Sayari A. (2016). Activated carbon with optimum pore sizedistribution for hydrogen storage. Carbon ; 99:289–94. https://doi.org/10.1016/j.carbon.2015.12.032.

Shafiq, M., Alazba, A.A. & Amin, M.T. (2018). Removal of heavy metals from wastewater using date palm as a biosorbent: A comparative review. Sains Malaysiana 47(1): 35-49. http://dx.doi.org/10.17576/jsm-2018-4701-05.

Tetra, O.N., Aziz, H., Emriadi, Ibrahim, S., Alif, A. (2018). Review ; superkapasitor berbahan dasar karbon aktif dan larutan ionic sebagai elektrolit. Jurnal Zarah, Vol. 6 No. 1 Halaman 39-46.

Https://ojs.umrah.ac.id/index.php/zarah/article/view/293/309.

Yang, J., Wu, J., Jiang, P., Xu, Q., Zhao, P., & He, S. (2015). A study of Phytolith-occluded carbon stock in Monopodial Bamboo in China. https://www.nature.com/articles/srep13292.

Zhao XY, Huang SS, Cao JP, Xi SC, Wei XY, Kamamoto J, et al. (2014). KOH activation of a HyperCoal to develop activated carbonsfor electric double-layer capacitors. Journal of Analytical and Applied Pyrolysis;105:116–121. https://doi.org/10.1016/j.jaap.2013.10.010.




DOI: https://doi.org/10.17969/rtp.v15i1.22733

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